Synthesis of the first-membered ring compound containing three tin atoms and one oxygen. The crystal structure of the species [O{Sn(C 6H 3Et 2-2,6) 2} 3]

Aerial oxidation of the novel homocyclic tetratin species [{SnAr 2} 3SnArBr] ( 1) [1] (Ar  C 6H 3Et 2-2,6) affords the tritin heterocycle [O{Sn(C 6H 3Et 2-2,6) 2} 3] ( 2), which has been crystallographically characterised; 2 is the first reported oxatristannacyclobutane, and the first heterocyclic...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 411; no. 1; pp. C3 - C6
Main Authors Cardin, Christine J., Cardin, David J., Convery, Maire A., Devereux, Michael M.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 02.07.1991
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Summary:Aerial oxidation of the novel homocyclic tetratin species [{SnAr 2} 3SnArBr] ( 1) [1] (Ar  C 6H 3Et 2-2,6) affords the tritin heterocycle [O{Sn(C 6H 3Et 2-2,6) 2} 3] ( 2), which has been crystallographically characterised; 2 is the first reported oxatristannacyclobutane, and the first heterocyclic tin species having both tintin and tinheteroatom bonds.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(91)86031-K