Complexation of rhodium(I) with hydrophosphorane derivatives of bicyclo[3.3.0]-1-phospha-2,8-dioxa-5-aza-octane

The interaction of hydrophosphorane derivatives of bicycloamidophosphite (BAP) with square-planar d 8 rhodium(I) complex [Rh(CO 2)Cl] 2 is studied. The structures of the complexes formed are discussed on the basis of IR, 31P and 13C NMR and X-ray electron spectral data.

Saved in:
Bibliographic Details
Published inJournal of organometallic chemistry Vol. 461; no. 1; pp. 229 - 232
Main Authors Gavrilov, K.N., Michel, I.S., Teleshev, A.T., Nifantyev, E.E.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 30.11.1993
Online AccessGet full text

Cover

More Information
Summary:The interaction of hydrophosphorane derivatives of bicycloamidophosphite (BAP) with square-planar d 8 rhodium(I) complex [Rh(CO 2)Cl] 2 is studied. The structures of the complexes formed are discussed on the basis of IR, 31P and 13C NMR and X-ray electron spectral data.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(93)83296-8