Relaxation effects in the mössbauer spectra of some seven-coordinate iron(III) complexes

Mössbauer studies have been carried out on a series of high-spin seven-coordinate complexes of iron(III). The group show interesting temperature-dependent properties which may be interpreted in terms of paramagnetic relaxation effects. A detailed analysis of these properties allows a direct correlat...

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Bibliographic Details
Published inThe Journal of physics and chemistry of solids Vol. 34; no. 2; pp. 277 - 282
Main Authors Deeney, F.A., Nelson, S.M.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 1973
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Summary:Mössbauer studies have been carried out on a series of high-spin seven-coordinate complexes of iron(III). The group show interesting temperature-dependent properties which may be interpreted in terms of paramagnetic relaxation effects. A detailed analysis of these properties allows a direct correlation to be drawn between the spectroscopic zero-field splitting and the quadrupole splitting for high-spin iron(III) complexes
ISSN:0022-3697
1879-2553
DOI:10.1016/0022-3697(73)90087-5