Surface faceting of vicinal SrTiO3(100)
We report on transformations of the vicinal (100) surface of single crystalline SrTiO3 upon annealing in air at high temperatures. The surface (decomposes) facets into a step and terrace (hill and valley) structure determined by the thermodynamic equilibrium state. It is demonstrated that the surfac...
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Published in | Materials today : proceedings Vol. 71; pp. 69 - 77 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier Ltd
2022
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Subjects | |
Online Access | Get full text |
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Summary: | We report on transformations of the vicinal (100) surface of single crystalline SrTiO3 upon annealing in air at high temperatures. The surface (decomposes) facets into a step and terrace (hill and valley) structure determined by the thermodynamic equilibrium state. It is demonstrated that the surface morphology can be fully tuned in the sub-micron range by controlling annealing temperatures and miscut angle. Step and terrace structures have been observed in the temperature range 1160–1420 °C. The surfaces were characterized by atomic force microscope, X-ray diffraction, transmission electron microscope, and X-ray photoelectron spectroscopy to assess the roles of temperature, miscut, defects and impurities on the final morphology. The slope of the steps is revealed by cross-sectioning of the facetted surface. |
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ISSN: | 2214-7853 2214-7853 |
DOI: | 10.1016/j.matpr.2022.08.283 |