Syntheses and the Beckmann Fission of Cyclic α-Hydroxyimino Ketones
A convenient method for the preparation of α-hydroxyimino cycloalkanones has been established by the reaction of cycloalkanones and nitrosyl chloride. ω-Cyanocarboxylic acids or their derivatives were obtained in good yield by the Beckmann rearrangement of these α-hydroxyimino ketones.
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| Published in | Bulletin of the Chemical Society of Japan Vol. 46; no. 11; pp. 3474 - 3477 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
The Chemical Society of Japan
01.11.1973
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| Online Access | Get full text |
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| Summary: | A convenient method for the preparation of α-hydroxyimino cycloalkanones has been established by the reaction of cycloalkanones and nitrosyl chloride. ω-Cyanocarboxylic acids or their derivatives were obtained in good yield by the Beckmann rearrangement of these α-hydroxyimino ketones. |
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| ISSN: | 0009-2673 1348-0634 |
| DOI: | 10.1246/bcsj.46.3474 |