Ni(II) N4-macrocycle grafted crown ether: caesium cobalt(III) bis(dicarbollide) coordination polymer

A mixture of a Ni(TMTAA) grafted crown ether and Cs[Co(C2B9H11)2] in toluene-CH2Cl2 affords a 1:1 complex, comprised of layers of infinite two-dimensional polymeric arrays separated by layers of the cobalticarborane anion which themselves form two B-H...Cs+ hydrogen interactions.

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) no. 1; pp. 16 - 17
Main Authors Malic, Nino, Nichols, Peter J, Raston, Colin L
Format Journal Article
LanguageEnglish
Published England 07.01.2002
Online AccessGet full text

Cover

Loading…
More Information
Summary:A mixture of a Ni(TMTAA) grafted crown ether and Cs[Co(C2B9H11)2] in toluene-CH2Cl2 affords a 1:1 complex, comprised of layers of infinite two-dimensional polymeric arrays separated by layers of the cobalticarborane anion which themselves form two B-H...Cs+ hydrogen interactions.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/b108162d