Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory
Several unimolecular photobase generators capable of catalyzing upconversion nanoparticle-assisted anionic thiol-epoxy click photopolymerization are presented. The fabricated polymers, with a curing depth of 11.8 cm, are dual-wavelength responsive and display shape memory function, showing great pot...
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Published in | Polymer chemistry Vol. 13; no. 21; pp. 348 - 352 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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Royal Society of Chemistry
31.05.2022
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Abstract | Several unimolecular photobase generators capable of catalyzing upconversion nanoparticle-assisted anionic thiol-epoxy click photopolymerization are presented. The fabricated polymers, with a curing depth of 11.8 cm, are dual-wavelength responsive and display shape memory function, showing great potential for the construction of smart medical devices and robots.
A photobase generator absorbing upconversion fluorescence can efficiently catalyze anionic thiol-epoxy click photopolymerization under 980 nm NIR light irradiation. |
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AbstractList | Several unimolecular photobase generators capable of catalyzing upconversion nanoparticle-assisted anionic thiol-epoxy click photopolymerization are presented. The fabricated polymers, with a curing depth of 11.8 cm, are dual-wavelength responsive and display shape memory function, showing great potential for the construction of smart medical devices and robots.
A photobase generator absorbing upconversion fluorescence can efficiently catalyze anionic thiol-epoxy click photopolymerization under 980 nm NIR light irradiation. Several unimolecular photobase generators capable of catalyzing upconversion nanoparticle-assisted anionic thiol-epoxy click photopolymerization are presented. The fabricated polymers, with a curing depth of 11.8 cm, are dual-wavelength responsive and display shape memory function, showing great potential for the construction of smart medical devices and robots. |
Author | Huang, Yaoxin Li, Zhiquan Liu, Xiaoxuan Li, Longji |
AuthorAffiliation | Guangdong Laboratory of Chemistry and Fine Chemical Industry Jieyang Center School of Materials and Energy Guangdong University of Technology |
AuthorAffiliation_xml | – name: Guangdong University of Technology – name: School of Materials and Energy – name: Guangdong Laboratory of Chemistry and Fine Chemical Industry Jieyang Center |
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SubjectTerms | Curing Nanoparticles Near infrared radiation Photopolymerization Polymer chemistry Shape memory |
Title | Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory |
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