Hydrocarbon Synthesis from CO2 and H2 Using the Ultrafine Iron-Containing Catalytic Systems Based on Carbonized Cellulose

Carbon materials were formed by the hydrothermal carbonization of cellulose, which were used as support for carbon dioxide hydrogenation catalysts (Fe/C and Fe-Mn/C). In the presence of these catalytic systems, CO2 conversion reached 50%. It is shown that the manganese introduction into the Fe-conta...

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Bibliographic Details
Published inEurasian chemico-technological journal Vol. 24; no. 2; p. 149
Main Authors Kulikova, M.V., Chudakova, M.V., Ivantsov, M.I., Dementyva, О.S., Maksimov, A.L.
Format Journal Article
LanguageEnglish
Published al-Farabi Kazakh National University 25.07.2022
Subjects
Carbon carrier
CO2 hydrogenation
Hydrothermal carbonization
Product distribution
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Summary:Carbon materials were formed by the hydrothermal carbonization of cellulose, which were used as support for carbon dioxide hydrogenation catalysts (Fe/C and Fe-Mn/C). In the presence of these catalytic systems, CO2 conversion reached 50%. It is shown that the manganese introduction into the Fe-containing catalytic system significantly affects the distribution of gaseous С1-С4 products and liquid С5+ hydrocarbons. Promotion leads to the suppression of methane formation and an increase in the proportion of C2-C4 light olefins in gaseous products, as well as to intensification of secondary processes with the formation of a significant amount of iso-structures in liquid products. The different distribution of С1-С6 alcohols in the oxygen-containing products on the Fe/C and Fe-Mn/C catalysts indicates the manganese effect on the routes of their formation.
ISSN:2522-4867
1562-3920
2522-4867
DOI:10.18321/ectj1327