Iron‐Catalyzed Carbonylation Reactions with Carbon Monoxide

The utilization of carbon monoxide (CO) as an inexpensive and indispensable C 1 feedstock for the efficient construction of diverse carbonylated compounds has been a subject of numerous studies for decades. Nowadays, transition metal‐catalyzed carbonylation represents a pivotal synthetic approach fo...

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Bibliographic Details
Published inAngewandte Chemie International Edition p. e202512346
Main Authors Sun, Kangkang, Lu, Guo‐Ping, Han, Wei, Beller, Matthias
Format Journal Article
LanguageEnglish
Published Germany 10.08.2025
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Summary:The utilization of carbon monoxide (CO) as an inexpensive and indispensable C 1 feedstock for the efficient construction of diverse carbonylated compounds has been a subject of numerous studies for decades. Nowadays, transition metal‐catalyzed carbonylation represents a pivotal synthetic approach for the generation of carbonyl‐containing molecules. Among the known catalysts for these transformations, non ‐noble metal‐based systems have garnered increasing interest in recent years due to their substantial advantages, including wide availability, low cost, and low toxicity. In this review, we have summarized and discussed original and recent developments in iron‐catalyzed carbonylative transformations, wherein CO is utilized as the C 1 feedstock.
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.202512346