Dipyridyl-Decorated Nitronyl Nitroxide-Dy III Single-Molecule Magnet with a Record Energy Barrier of 146 K

A nitronyl nitroxide biradical with a capping N-donor group was discovered to improve single-molecule-magnet behavior of the Dy-biradical cluster, generating a magnetic reversal barrier of 146 K. As far as we know, the effective energy barrier of the Dy compound is largest in the nitronyl nitroxide...

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Bibliographic Details
Published inInorganic chemistry Vol. 60; no. 11; pp. 7622 - 7626
Main Authors Li, Hongdao, Jing, Pei, Lu, Jiao, Xie, Jing, Zhai, Lijun, Xi, Lu
Format Journal Article
LanguageEnglish
Published United States 07.06.2021
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Summary:A nitronyl nitroxide biradical with a capping N-donor group was discovered to improve single-molecule-magnet behavior of the Dy-biradical cluster, generating a magnetic reversal barrier of 146 K. As far as we know, the effective energy barrier of the Dy compound is largest in the nitronyl nitroxide 4f system by far.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.1c00809