Dissociative electron attachment and Ar+ reaction with chromium hexacarbonyl, 296-400 K

Dissociative electron attachment rate constants have been measured for Cr(CO)6 under thermal conditions, 296-400 K, yielding Cr(CO)5- product. At 296 K, 2.92 ± 0.70 cm3 s-1 was measured and a small decrease with temperature was observed (2.72 ± 0.70 cm3 s-1 at 400 K). We additionally determined the...

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Published inThe Journal of chemical physics Vol. 161; no. 12
Main Authors Miller, Thomas M, Rodriguez, Virginia G, Ard, Shaun G, Viggiano, Albert A, Shuman, Nicholas S
Format Journal Article
LanguageEnglish
Published United States 28.09.2024
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Summary:Dissociative electron attachment rate constants have been measured for Cr(CO)6 under thermal conditions, 296-400 K, yielding Cr(CO)5- product. At 296 K, 2.92 ± 0.70 cm3 s-1 was measured and a small decrease with temperature was observed (2.72 ± 0.70 cm3 s-1 at 400 K). We additionally determined the cation products of Ar+ reacting with Cr(CO)6.
ISSN:1089-7690
DOI:10.1063/5.0232322