Silver-Catalyzed Direct C${{_{sp{^{2}}}}}$H Phosphorylation of Indoles Leading to Phosphoindoles

The silver carbonate‐catalyzed direct C${{_{sp{^{2}}}$H phosphorylation of indoles in the presence of magnesium nitrate is described. The reaction affords selectively phosphonoindoles in moderate to good yields through a radical process. This protocol provides an efficient and general method for th...

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Published inAdvanced synthesis & catalysis Vol. 358; no. 11; pp. 1753 - 1758
Main Authors Sun, Wang-Bin, Xue, Jian-Fei, Zhang, Guo-Yu, Zeng, Run-Sheng, An, Li-Tao, Zhang, Pei-Zhi, Zou, Jian-Ping
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 02.06.2016
WILEY‐VCH Verlag
Subjects
Catalysis
Indoles
Magnesium
Nitrates
Phosphorylation
radical reactions
Radicals
silver carbonate
Synthesis
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Summary:The silver carbonate‐catalyzed direct C${{_{sp{^{2}}}$H phosphorylation of indoles in the presence of magnesium nitrate is described. The reaction affords selectively phosphonoindoles in moderate to good yields through a radical process. This protocol provides an efficient and general method for the preparation of 2‐ and 3‐phosphorylated indoles.
Bibliography:National Natural Science Foundation of China - No. Nos. 20772088, 21172163, 21472133
Priority Academic Program Development of Jiangsu Higher Education
Institutions & State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials
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ark:/67375/WNG-QR2KL46L-L
ArticleID:ADSC201600001
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201600001