Development of an angle-adjustable photonic crystal fluorescence platform for sensitive detection of oxytetracycline

• Published in: Chemical communications (Cambridge, England) Vol. 60; no. 62; pp. 8115 - 8118
• Main Authors: Huang, Yunhuan, Zhang, Jiaheng, Sui, Bo, Chai, Guobi, Yu, Ajuan, Chen, Sheng, Zhang, Miaomiao, Zhang, Shusheng, Zhang, Yanhao, Zhao, Wuduo
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 30.07.2024
• Subjects: Angle of reflection; Angular resolution; Emission; Energy levels; Fluorescence; Incidence angle; Microcavities; Optical resonance; Oxytetracycline; Photonic crystals
• ISSN: 1359-7345; 1364-548X; 1364-548X
• DOI: 10.1039/d4cc02363c

We pioneered an angle-adjustable photonic crystal fluorescence platform (APC-Fluor) that integrates PCs, an angular resolution spectrometer and a strategically aligned laser source. This configuration, featuring a coaxial rotating swing arm, allows for precise control over the angles of incidence and emission. The presence of photonic crystal microcavities facilitates the dispersion of fluorescent materials and promotes the transition of electrons from the excited state to the lowest vibrational energy level. The optical resonance effect triggered by modulating the alignment of the reflection peaks of the photonic crystals with the emission peaks of the fluorescent materials can significantly enhance the fluorescence intensity. Compared with the single BSA-AuNCs, the optimized fluorescence intensity can be significantly increased by 11.9-fold. The APC-Fluor system showcases rapid and highly sensitive detection capabilities for oxytetracycline (OTC), exhibiting a response across a concentration range from 2 to 1 × 10 nM and achieving a notably low detection limit of 1.03 nM.