Front Cover: A Guide for the Design of Functional Polyaromatic Organophosphorus Materials (Chem. Eur. J. 56/2017)

Fusing six‐membered phosphorus heterocycles with different (hetero)aromatic rings provides materials with an outstanding potential for multifunctional applications. Our investigations reveal the key parameters to obtain polycyclic architectures based on six‐membered phosphorus heterocycles with, amo...

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Bibliographic Details
Published inChemistry : a European journal Vol. 23; no. 56; p. 13814
Main Authors Hindenberg, Philip, López‐Andarias, Alicia, Rominger, Frank, de Cózar, Abel, Romero‐Nieto, Carlos
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 09.10.2017
Subjects
Aromatic compounds
density functional calculations
Fluorescence
heterocycles
optoelectronic properties
organophosphorus materials
Phosphorus
reaction mechanisms
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Summary:Fusing six‐membered phosphorus heterocycles with different (hetero)aromatic rings provides materials with an outstanding potential for multifunctional applications. Our investigations reveal the key parameters to obtain polycyclic architectures based on six‐membered phosphorus heterocycles with, among others, electron‐accepting properties, fluorescence quantum yields up to 0.8, and versatile means to control the 3D molecular arrangement through phosphorus post‐functionalization. More information can be found in the Full Paper by A. de Cózar, C. Romero‐Nieto et al. on page 13919.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201703449