2,3-Diruthenocenylcyclopropenone

In the title compound, [Ru 2 (C 5 H 5 ) 2 (C 13 H 8 O)], the Ru—C bond lengths in the two ruthenocenyl moieties are in the range of 2.155 (4)–2.196 (3) Å. Both cyclopentadienyl (Cp) rings are planar and parallel with staggered (18.6 °) and eclipsed (3.1°) conformations between the mutual orientation...

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Bibliographic Details
Published inIUCrData Vol. 2; no. 9; p. x171358
Main Authors Sánchez García, Jessica J., Flores-Alamo, Marcos, Klimova, Elena I.
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 28.09.2017
Subjects
crystal structure
diruthenocenylcyclopropenone
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Summary:In the title compound, [Ru 2 (C 5 H 5 ) 2 (C 13 H 8 O)], the Ru—C bond lengths in the two ruthenocenyl moieties are in the range of 2.155 (4)–2.196 (3) Å. Both cyclopentadienyl (Cp) rings are planar and parallel with staggered (18.6 °) and eclipsed (3.1°) conformations between the mutual orientations of rings in the independent sandwiches of each ruthenocenyl molecule. In the crystal, there are intermolecular C—H...O hydrogen bonds between Cp carbon donor atoms and the cyclopropenone O atom of adjacent molecules, forming R 2 2 (14) and R 6 6 (38) motifs along the b and c axes.
ISSN:2414-3146
2414-3146
DOI:10.1107/S241431461701358X