Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access to meta-Substituted Phenols
Ein vielseitiger dikationischer Palladium(II)‐Katalysator mit 6,6′‐Dimethyl‐2,2′‐bipyridin als Ligand vermittelt sowohl aerobe oxidative Heck‐Kupplungen als auch Dehydrierungen von Cyclohexenonen. Diese Reaktionen können für die direkte Synthese meta‐substituierter Phenole zu einer Eintopfsequenz ko...
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| Published in | Angewandte Chemie Vol. 125; no. 13; pp. 3760 - 3763 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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Weinheim
WILEY-VCH Verlag
25.03.2013
WILEY‐VCH Verlag |
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| Abstract | Ein vielseitiger dikationischer Palladium(II)‐Katalysator mit 6,6′‐Dimethyl‐2,2′‐bipyridin als Ligand vermittelt sowohl aerobe oxidative Heck‐Kupplungen als auch Dehydrierungen von Cyclohexenonen. Diese Reaktionen können für die direkte Synthese meta‐substituierter Phenole zu einer Eintopfsequenz kombiniert werden (siehe Schema). |
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| AbstractList | Ein vielseitiger dikationischer Palladium(II)‐Katalysator mit 6,6′‐Dimethyl‐2,2′‐bipyridin als Ligand vermittelt sowohl aerobe oxidative Heck‐Kupplungen als auch Dehydrierungen von Cyclohexenonen. Diese Reaktionen können für die direkte Synthese meta‐substituierter Phenole zu einer Eintopfsequenz kombiniert werden (siehe Schema). |
| Author | Zheng, Changwu Izawa, Yusuke Stahl, Shannon S. |
| Author_xml | – sequence: 1 givenname: Yusuke surname: Izawa fullname: Izawa, Yusuke organization: Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706 (USA) – sequence: 2 givenname: Changwu surname: Zheng fullname: Zheng, Changwu organization: Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706 (USA) – sequence: 3 givenname: Shannon S. surname: Stahl fullname: Stahl, Shannon S. email: stahl@chem.wisc.edu organization: Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706 (USA) |
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| Notes | Shanghai Institute of Organic Chemistry ark:/67375/WNG-398G4J5Q-D NIH - No. R01 GM100143 Mitsubishi Chemical Corporation istex:1E0D02E95F18D5F1AE104ADAFD45648165DCAB65 ArticleID:ANGE201209457 We thank Dr. Doris Pun for assistance in product purification. Financial support was provided by the NIH (R01 GM100143), Mitsubishi Chemical Corporation, and the Shanghai Institute of Organic Chemistry (postdoctoral fellowship for C.W.Z.). These authors contributed equally to this work. |
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| Title | Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access to meta-Substituted Phenols |
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