Synthesis of 2-methoxy-1-tetrazolylmethyldiazene 1-oxide derivatives

New derivatives of 2-methoxy-1-tetrazolylmethyldiazene 1-oxides bearing additional explosophoric groups were synthesized. The reactions of the appropriate aminotetrazoles with trinitromethane in the presence of paraformaldehyde gave trinitroethylamine derivatives and nitration of these aminotetrazol...

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Bibliographic Details
Published inRussian chemical bulletin Vol. 73; no. 5; pp. 1321 - 1327
Main Authors Nikitin, S. V., Smirnov, G. A.
Format Journal Article
LanguageEnglish
Published New York Springer US 01.05.2024
Springer Nature B.V
Subjects
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Nitration
Organic Chemistry
tetrazol-2-yl)methyldiazene 1-oxide
nitrosation
2-alkoxydiazene 1-oxides
substituted
1- and 2-substituted tetrazoles
diazene diolates
trinitromethane
azo compounds
nitration
oxidation
trinitroethylaminotetrazoles
2-methoxy-1-(5-nitro-2
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Summary:New derivatives of 2-methoxy-1-tetrazolylmethyldiazene 1-oxides bearing additional explosophoric groups were synthesized. The reactions of the appropriate aminotetrazoles with trinitromethane in the presence of paraformaldehyde gave trinitroethylamine derivatives and nitration of these aminotetrazoles with dinitrogen pentoxide led to nitramines.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-024-4249-z