Synthesis of Nitrogen-Containing Heterocycles from Estragole

Reaction of estragole, a natural allyl benzene, with nitriles gave novel 3-methyl-1-(methylsulfanyl)-2-azaspiro[4.5]deca-1,6,9-trien-8-one, 10,11-dimethoxy-6-methyl-1,5,6,12 b -tetrahydrodibenzo[ d , f ]indole-2,8-dione, and 2-methyl-2,7,7 a ,8-tetrahydropyrrolo[3,2- l ]acridin-6(3 H )-one.

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Bibliographic Details
Published inRussian journal of organic chemistry Vol. 58; no. 11; pp. 1575 - 1580
Main Authors Smolyak, A. A., Shklyaev, Yu. V.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.11.2022
Springer Nature
Springer Nature B.V
Subjects
Benzene
Chemistry
Chemistry and Materials Science
Chemistry, Organic
Nitriles
Organic Chemistry
Physical Sciences
Science & Technology
nitrogen-containing heterocycles
nitriles
the Ritter reaction
estragole
3-METHYL-3,4-DIHYDROISOQUINOLINES
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Summary:Reaction of estragole, a natural allyl benzene, with nitriles gave novel 3-methyl-1-(methylsulfanyl)-2-azaspiro[4.5]deca-1,6,9-trien-8-one, 10,11-dimethoxy-6-methyl-1,5,6,12 b -tetrahydrodibenzo[ d , f ]indole-2,8-dione, and 2-methyl-2,7,7 a ,8-tetrahydropyrrolo[3,2- l ]acridin-6(3 H )-one.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428022110033