Thermal and oxidative stability of Sacha Inchi oil and capsules formed with biopolymers analyzed by DSC and 1H NMR

• Published in: Journal of thermal analysis and calorimetry Vol. 131; no. 3; pp. 2093 - 2104
• Main Authors: Vicente, Juarez, Cappato, Leandro Pereira, de Araújo Calado, Verônica Maria, de Carvalho, Mario Geraldo, Garcia-Rojas, Edwin Elard
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 2018; Springer Nature B.V
• Subjects: Analytical Chemistry; Biopolymers; Chemistry; Chemistry and Materials Science; Differential scanning calorimetry; Edible oils; Inorganic Chemistry; Kinetics; Magnetic induction; Measurement Science and Instrumentation; NMR; Nuclear magnetic resonance; Oils & fats; Oxidation; Physical Chemistry; Polymer Sciences; Stability analysis; Sacha Inchi oil; Omega-3 stability; DSC; H NMR; Oxidized compounds
• ISSN: 1388-6150; 1588-2926
• DOI: 10.1007/s10973-017-6759-5

The oxidative stability of edible oils is an important feature to know due the undesirable changes that can occur in the storage. In this way, the oxidative induction time (OIT) value is an indicative to prevent this effect. The objectives of this study were to evaluate the omega-3 content and kinetic parameters of Sacha Inchi oil (SIO) and capsules that are formed with biopolymers, in addition, there were analyzed with differential scanning calorimetry (DSC) and proton nuclear magnetic resonance ( 1 H NMR). The SIO and capsules, formed using an emulsion, were analyzed with DSC in an oxygen atmosphere to determine the OIT value in isothermal conditions at 100, 120 and 150 °C. The kinetic parameters (activation energy, pre-exponential factor and z value) of SIO were obtained, and the stability time was predicted at different temperatures. The 1 H NMR spectra enabled us to assess the identification and percentage relative before and after the isothermal DSC oxidation of omega-3 concentration and formation of their oxidized compounds. (E-E)-2,4-Alkadienals were the primary oxidized compound and is strongly correlated with the decrease in omega-3 content. Isothermal DSC is a useful to determine the OIT (min) and kinetic parameters to predict the stability oxidation in different edible oils and thus prevent the inadequate consumption of edible oils oxidized.