A rapid and greener MOF-2 catalyzed Knoevenagel reaction at room temperature

An efficient MOF-2 [Zn2(BDC)2] catalyzed process of Knoevenagel reaction has developed at room temperature using an eco-friendly reaction medium. The different substituted aldehydes studied with malononitrile as substrates and the derivatives were obtained in excellent yields with good tolerance of...

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Bibliographic Details
Published inTetrahedron Vol. 152; pp. 133818 - 133823
Main Authors Kadu, Vikas D., Kotali, Bhagyashree C., Wadkar, Pooja S., Thokal, Machhindra S., Godase, Rajkumar K.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 15.02.2024
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
SELECTIVE OXIDATION
Terephthalic acid
H2BDC
Metal-organic framework
MOF-2
Knoevenagel reaction
Zn-BDC
WATER
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Summary:An efficient MOF-2 [Zn2(BDC)2] catalyzed process of Knoevenagel reaction has developed at room temperature using an eco-friendly reaction medium. The different substituted aldehydes studied with malononitrile as substrates and the derivatives were obtained in excellent yields with good tolerance of functional groups in the established Knoevenagel condensation approach.
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2023.133818