One single catalyst, Pd(OAc)2, for two sequential very different steps: allylic alcohol oxidation-Heck reaction. Access to functionalised alpha,beta-unsaturated ketones

A single addition of the catalyst, Pd(OAc)(2), was realised to mediate two transformations as different as allylic alcohol oxidation under O(2) and C-C bond formation of the Heck type, to give substituted alpha,beta-unsaturated ketones without intermediate purification.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 44; pp. 5830 - 5832
Main Authors Batt, Frédéric, Gozzi, Christel, Fache, Fabienne
Format Journal Article
LanguageEnglish
Published England 30.11.2008
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Summary:A single addition of the catalyst, Pd(OAc)(2), was realised to mediate two transformations as different as allylic alcohol oxidation under O(2) and C-C bond formation of the Heck type, to give substituted alpha,beta-unsaturated ketones without intermediate purification.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/b810538c