Monoclinic polymorph of trans -tetraaquabis[(4-pyridylsulfanyl)acetato- κN ]cobalt(II)

The crystal structure of the title compound, [Co(C7H6NO2S)2(H2O)4], is a polymorph of the structure first reported by Du, Zhao & Wang [(2004). Dalton Trans, pp. 2065-2072]. The asymmetric unit of the title compound contains one half-molecule; the CoII atom lies on an inversion centre in a distor...

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Published inActa crystallographica. Section E, Structure reports online Vol. 64; no. 8; p. m1089
Main Authors Mikloš, Dušan, Miklovič, Jozef, Moncol, Jan, Segľa, Peter, Koman, Marian
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.08.2008
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Summary:The crystal structure of the title compound, [Co(C7H6NO2S)2(H2O)4], is a polymorph of the structure first reported by Du, Zhao & Wang [(2004). Dalton Trans, pp. 2065-2072]. The asymmetric unit of the title compound contains one half-molecule; the CoII atom lies on an inversion centre in a distorted octahedral geometry coordinated by two N atoms of the pyridine rings of the 4-pyridylthioacetate anions and four O atoms of water molecules. In the crystal structure, intermolecular O-H...O hydrogen bonds link the molecules, forming a three-dimensional network.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808023593