Synthesis and spectroscopic characterization of polynuclear silver(I) complex with 2,2'-biquinoline
Polynuclear silver(I) complex, [Ag(NO3-O)(2,2'-bq-N,N')]n, was synthesized by the reaction of equimolar amount of silver(I) nitrate and 2,2'-biquinoline (2,2'-bq) in ethanol at room temperature. The characterization of the complex was established on the basis of elemental microan...
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Published in | The university thought. Publication in natural sciences Vol. 10; no. 1; pp. 26 - 30 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
University of Priština - Faculty of Natural Science and Mathematics, Kosovska Mitrovica
2020
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Subjects | |
Online Access | Get full text |
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Summary: | Polynuclear silver(I) complex, [Ag(NO3-O)(2,2'-bq-N,N')]n, was synthesized by the reaction of equimolar amount of silver(I) nitrate and 2,2'-biquinoline (2,2'-bq) in ethanol at room temperature. The characterization of the complex was established on the basis of elemental microanalysis, IR, NMR (1H and 13C) and UV-Vis spectroscopic techniques. The results of spectroscopic analyses revealed that in [Ag(NO3-O)(2,2'-bq-N,N')]n complex, 2,2'-bq ligand behaves as a chelate, while the remaining coordination sites are occupied by the oxygen atoms of two nitrates. |
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ISSN: | 1450-7226 2560-3094 |
DOI: | 10.5937/univtho10-25898 |