Synthesis and spectroscopic characterization of polynuclear silver(I) complex with 2,2'-biquinoline

Polynuclear silver(I) complex, [Ag(NO3-O)(2,2'-bq-N,N')]n, was synthesized by the reaction of equimolar amount of silver(I) nitrate and 2,2'-biquinoline (2,2'-bq) in ethanol at room temperature. The characterization of the complex was established on the basis of elemental microan...

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Published inThe university thought. Publication in natural sciences Vol. 10; no. 1; pp. 26 - 30
Main Authors Gurešić, Dejan, Đurić, Sonja, Andrejević, Tina, Popsavin, Mirjana, Glišić, Biljana
Format Journal Article
LanguageEnglish
Published University of Priština - Faculty of Natural Science and Mathematics, Kosovska Mitrovica 2020
Subjects
n-heterocycles
polynuclear complexes
silver(i) complexes
spectroscopy
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Summary:Polynuclear silver(I) complex, [Ag(NO3-O)(2,2'-bq-N,N')]n, was synthesized by the reaction of equimolar amount of silver(I) nitrate and 2,2'-biquinoline (2,2'-bq) in ethanol at room temperature. The characterization of the complex was established on the basis of elemental microanalysis, IR, NMR (1H and 13C) and UV-Vis spectroscopic techniques. The results of spectroscopic analyses revealed that in [Ag(NO3-O)(2,2'-bq-N,N')]n complex, 2,2'-bq ligand behaves as a chelate, while the remaining coordination sites are occupied by the oxygen atoms of two nitrates.
ISSN:1450-7226
2560-3094
DOI:10.5937/univtho10-25898