Thermal decomposition of inclusion compounds on the base of the metal–organic framework [Zn4(dmf)(ur)2(ndc)4] Part I

• Published in: Journal of thermal analysis and calorimetry Vol. 117; no. 2; pp. 747 - 753
• Main Authors: Logvinenko, Vladimir A., Sapchenko, Sergey A., Fedin, Vladimir P.
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 2014
• Subjects: Analytical Chemistry; Chemistry; Chemistry and Materials Science; Inorganic Chemistry; Measurement Science and Instrumentation; Physical Chemistry; Polymer Sciences; Kinetic stability; Coordination compounds; Inclusion compounds; Metal–organic frameworks; Non-isothermal kinetics
• ISSN: 1388-6150; 1588-2926
• DOI: 10.1007/s10973-014-3827-y

Inclusion compounds based on metal–organic frameworks (MOFs) have promising practical applications in gas storage, the separation, and fine purification of substances, and also in catalysis. These MOFs are crystalline compounds consisting of metal ions coordinated by bridging organic ligands with the formation of porous structures. We study the kinetic stability of two inclusion compounds on the base of the new framework: [Zn 4 (dmf)(ur) 2 (ndc) 4 ]·6C 6 H 6 and [Zn 4 (dmf)(ur) 2 (ndc) 4 ]·5C 6 H 5 CH 3 (ndc 2−  = 2,6-naphtalenedicarboxylate, ur = hexamethylentetramin, dmf =  N , N ′-dimethylformamide). The inclusion compound with benzene is more stable than the compound with toluene. The reduced stability of the toluene compound may be connected with the toluene molecule’s shape: the C 6 H 5 CH 3 molecule is more bulky and asymmetric than the C 6 H 6 molecule; the MOF matrix structure must be greatly distorted to include the toluene molecules and the compound stability decreases.