Inside Back Cover: Visible-Light-Induced Click Chemistry (Angew. Chem. Int. Ed. 35/2015)

An ultrarapid visible-light-driven method for catalyst-free ligation is reported. In their Communication on page10284ff., C. Barner-Kowollik and co-workers describe a highly efficient conjugation between an azirine moiety (white) and diverse dipolarophiles (red) under irradiation from blue LEDs. Fol...

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Published inAngewandte Chemie International Edition Vol. 54; no. 35; p. 10375
Main Authors Mueller, Jan O., Schmidt, Friedrich G., Blinco, James P., Barner-Kowollik, Christopher
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 24.08.2015
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
azirine
click chemistry
photochemistry
polymer ligation
visible light
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Abstract An ultrarapid visible-light-driven method for catalyst-free ligation is reported. In their Communication on page10284ff., C. Barner-Kowollik and co-workers describe a highly efficient conjugation between an azirine moiety (white) and diverse dipolarophiles (red) under irradiation from blue LEDs. Following the photogeneration of a nitrile ylide (cyan structure), complete conversion into the cycloadduct takes place through a click-type reaction.
AbstractList An ultrarapid visible-light-driven method for catalyst-free ligation is reported. In their Communication on page10284ff., C. Barner-Kowollik and co-workers describe a highly efficient conjugation between an azirine moiety (white) and diverse dipolarophiles (red) under irradiation from blue LEDs. Following the photogeneration of a nitrile ylide (cyan structure), complete conversion into the cycloadduct takes place through a click-type reaction.
Author Blinco, James P.
Schmidt, Friedrich G.
Barner-Kowollik, Christopher
Mueller, Jan O.
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  givenname: James P.
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  organization: Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstrasse 18, 76128 Karlsruhe (Germany)
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SubjectTerms azirine
click chemistry
photochemistry
polymer ligation
visible light
Title Inside Back Cover: Visible-Light-Induced Click Chemistry (Angew. Chem. Int. Ed. 35/2015)
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