Inside Back Cover: Visible-Light-Induced Click Chemistry (Angew. Chem. Int. Ed. 35/2015)

An ultrarapid visible-light-driven method for catalyst-free ligation is reported. In their Communication on page10284ff., C. Barner-Kowollik and co-workers describe a highly efficient conjugation between an azirine moiety (white) and diverse dipolarophiles (red) under irradiation from blue LEDs. Fol...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 54; no. 35; p. 10375
Main Authors Mueller, Jan O., Schmidt, Friedrich G., Blinco, James P., Barner-Kowollik, Christopher
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 24.08.2015
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
azirine
click chemistry
photochemistry
polymer ligation
visible light
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Summary:An ultrarapid visible-light-driven method for catalyst-free ligation is reported. In their Communication on page10284ff., C. Barner-Kowollik and co-workers describe a highly efficient conjugation between an azirine moiety (white) and diverse dipolarophiles (red) under irradiation from blue LEDs. Following the photogeneration of a nitrile ylide (cyan structure), complete conversion into the cycloadduct takes place through a click-type reaction.
Bibliography:ArticleID:ANIE201506194
istex:52CC688C8AA1DCF9205660447227380311999D2D
ark:/67375/WNG-DSJ29GP2-S
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201506194