Energy efficiency and electrochemical characteristic assessment of PEMFC-supercapacitor hybridization via railway profile

• Published in: International journal of hydrogen energy Vol. 82; pp. 73 - 88
• Main Authors: Maiket, Yaowaret, Yeetsorn, Rungsima, Sumpavakup, Chaiyut, Hissel, Daniel
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 11.09.2024
• Subjects: Cyclic voltammetry; Electrochemical impedance spectroscopy; Fuel cell train; Hydrogen train; PEMFC hybridization; Stress test profile; Supercapacitors; Ultracapacitor; Cyclic voltammetry; Ultracapacitor; PEMFC hybridization; Supercapacitors; Hydrogen train; Fuel cell train; Stress test profile; Electrochemical impedance spectroscopy
• ISSN: 0360-3199
• DOI: 10.1016/j.ijhydene.2024.07.369

Electric trains equipped with efficient electric motors and powered by high-capacity hydrogen fuel cells are a choice of the global transportation industry to accelerate the global transition to a low-carbon transportation system. The operation of distinct vehicle types in varying geographical regions is characterized by unique features. Concurrently, the continually fluctuating demand for electricity necessitates the utilization of fuel cells in conjunction with energy storage devices. Thus, this study centers on examining the role of the PEMFC-supercapacitor direct hybridization system within the authentic driving profile of the subway in the Bangkok metropolitan region. The supercapacitor within the hybridization system serves as an energy management device, enhancing the durability of fuel cells when subjected to diverse load demands associated with train propulsion. In order to validate this hypothesis, an MRT (Mass Rapid Transit) protocol was formulated to emulate and serve as the load demand for the investigation, and then the PEMFC-supercapacitor direct hybridization system was operated using the created profile. Subsequently, the hybridization system undergoes electrochemical characterizations and fuel cell performance tests for diagnostic purposes. Empirical findings validated that the supercapacitor operates as a filter, generating a stable voltage response to varying load requirements, and possesses the capability to assimilate energy originating from regenerative braking. The integration of supercapacitors in stabilizing the operational parameters of proton exchange membrane fuel cells (PEMFCs) has markedly prolonged their operational lifespan. This assertion is substantiated by voltage signal analysis, which demonstrated a negligible increase in surface resistance of merely 0.23%, as depicted by Nyquist plots. Furthermore, cyclic voltammetry revealed that the system attained a peak electrochemical surface area (ECSA) of 0.0089 (106 cm2/mg of Pt). The information presented in this article constitutes data that has been minimally explored in existing research. Specifically, the study concentrates on the practical driving pattern of electric trains. Consequently, experimental results were deemed advantageous for the advancement of heavy-duty electric vehicles. [Display omitted] •Exploring the relationship between the utilization of an energy storage device as a SC and energy generation as a PEMFC.•Establishing a connection between the authentic current profile of an MRT metro system and an accelerated stress test.•Examining the electrochemical reactions within fuel cells, drawing upon operational data from the transportation sector.