Synthesis of xonotlite using quartz glass powder waste as a silicon source

• Published in: Ceramics international Vol. 50; no. 20; pp. 39186 - 39192
• Main Authors: Liu, Wengang, Zhang, RuiRui, Liu, Wenbao, Li, Weichao, Wang, Shuaichao
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.10.2024
• Subjects: Hydrothermal synthesis; Quartz glass powder; Transformation mechanism; Xonotlite; Hydrothermal synthesis; Quartz glass powder; Transformation mechanism; Xonotlite
• ISSN: 0272-8842
• DOI: 10.1016/j.ceramint.2024.07.287

Quartz glass powder is a type of silicon-rich industrial waste. Accumulation of this waste has led to resource wastage and environmental pollution. In this paper, quartz glass powder is used as raw material for preparing xonotlite through hydrothermal synthesis. The effects of Ca/Si (C/S) molar ratio, liquid/solid ratio, reaction temperature, and reaction time on the conversion of quartz are studied. The phase and structural changes of glass powder are analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Based on this, the conversion mechanism of quartz in glass powder is explained. The dissolution rate of quartz in an alkaline solution is a critical factor that restricts hydrothermal reactions. The conversion rate of quartz can be effectively increased by raising reaction temperature and extending reaction time. When the reaction temperature is 240 °C and the reaction time reaches 14 h, the conversion of quartz can reach 94.5 wt%. This study reveals the conversion mechanism of quartz in hydrothermal reactions and provides a theoretical basis for the efficient utilization of glass powder.