Investigation into experimental conditions and factors for cyclohexane oxidation with VO(acac)2

The catalytic activity of VO(acac) 2 for the cyclohexane(Cy) oxidation was studied. The effects of various parameters, such as the amounts of H 2 O 2 , HNO 3 , H 2 O and Cy were investigated. The highest total turnover number(TON) is 234, which can be increased to 353, 342 and 403, respectively with...

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Bibliographic Details
Published inChemical research in Chinese universities Vol. 30; no. 6; pp. 991 - 996
Main Authors Ma, Xitong, Xing, Na, Wu, Qiong, Xu, Liting, Xing, Yongheng
Format Journal Article
LanguageEnglish
Published Heidelberg Jilin University and The Editorial Department of Chemical Research in Chinese Universities 01.12.2014
College of Chemistry and Chemical Engineering, Liaoning Normal University,Dalian 116029, P.R.China
Subjects
Analytical Chemistry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Inorganic Chemistry
Organic Chemistry
Physical Chemistry
Additive
Phthalic acid
Cyclohexane oxidation
VO(acac)
Mechanism
VO(acac)2
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Summary:The catalytic activity of VO(acac) 2 for the cyclohexane(Cy) oxidation was studied. The effects of various parameters, such as the amounts of H 2 O 2 , HNO 3 , H 2 O and Cy were investigated. The highest total turnover number(TON) is 234, which can be increased to 353, 342 and 403, respectively with the adding of o -phthalic, m -phthalic or p -phthalic acid. A reaction mechanism was also supposed primarily.
ISSN:1005-9040
2210-3171
DOI:10.1007/s40242-014-4188-6