Evolution characteristic and mechanism of microstructure, hydraulic and mechanical behaviors of sandstone treated by acid-rock reaction: Application of in-situ leaching of uranium deposits

• Published in: Journal of hydrology (Amsterdam) Vol. 643; p. 131948
• Main Authors: Hu, Mingwei, Niu, Qinghe, Yuan, Wei, Wang, Wei, Chang, Jiangfang, Du, Zhigang, Wang, Qizhi, Zheng, Yongxiang, Shangguan, Shuantong, Qi, Xiaofei, Ji, Zhongmin, Ma, Kaiyuan, He, Jiabin, Wang, Zhenkang, Yao, Yongzhi
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.2024
• Subjects: Acid-rock reaction; Energy evolution; Mineral characteristic; Permeability; Pore structure; Reservoir stimulation; Acid-rock reaction; Reservoir stimulation; Energy evolution; Mineral characteristic; Permeability; Pore structure
• ISSN: 0022-1694
• DOI: 10.1016/j.jhydrol.2024.131948

•Changes in mineral composition induced by acid-rock reaction promote the pore development and increase the permeability.•Acid-rock reaction weakens the mechanical properties of sandstone and strengthens its plasticity.•The evolution laws of microstructure, hydraulic and mechanical behaviors of sandstone are controlled by the acid concentration and reaction time.•Suggestions for optimizing the in-situ leaching mining process of uranium deposit are proposed. The main difficulty in understanding the effects of chemical-physical composite stimulation for low-permeability sandstone-type uranium deposits is clarifying the influence of acidification on pore response mechanism and permeability-mechanical properties evolution during loading-deformation-failure process. Therefore, the acid-rock reaction experiment was first performed, the multiple testing methods (X-ray Diffraction, thin-section identification, high-pressure mercury intrusion porosimetry, stress-seepage coupling experiment) were then conducted, the evolution laws and mechanisms of reservoir physical characteristics after acidification were finally clarified. Results show that after the acid-rock reaction, the contents of calcite, feldspar and kaolinite of samples are decreased and the quartz content is increased, the permeabilities of samples are all promoted, the peak strength, elastic modulus, and shear modulus of samples are reduced and the Poisson’s ratio is raised. The acid-rock reaction changes the energy storage performance and promotes the plasticization of samples. It is suggested to adopt a lower sulfuric acid concentration (2 g/L) and longer reaction time (>45 d) for the ISL of uranium deposits. This work has important theoretical and practical significance for an in-depth understanding of the enhanced mining of low-permeability sandstone-type uranium deposits.