Laser sintering of polyamide 12 with limited thermal degradation

• Published in: Journal of manufacturing processes Vol. 124; pp. 834 - 842
• Main Authors: Gruber, Piotr, Kubeczek, Aleksander, Olejarczyk, Michał, Ziółkowski, Grzegorz, Antończak, Arkadiusz J.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 30.08.2024
• Subjects: Dual beam laser sintering; GPC; MFR; Polyamide PA12; Polymer degradation; Polymer laser sintering (pLS); Tensile test; XCT; Polymer laser sintering (pLS); Polymer degradation; Dual beam laser sintering; Tensile test; XCT; MFR; GPC; Polyamide PA12
• ISSN: 1526-6125; 2212-4616
• DOI: 10.1016/j.jmapro.2024.06.056

The paper presents, for the first time, the results of PA12 polyamide sintering using the original method of Dual Beam Laser Sintering of polymers (DBLS). The DBLS method, which is a modification of the standard polymer Laser Sintering (pLS) approach, allows to reduce the thermal degradation of the polymer by using selective (in terms of powder volume and process time) heating the material with laser radiation. The paper presents both the properties of sintered parts and the analysis of the degree of thermal degradation of post-process powders. Examination of the sintered parts included X-ray computed tomography (XCT) to visualize and analyze their porosity and a tensile test. Post-process powders were evaluated by Gel Permeation Chromatography (GPC), Melt Flow Rate (MFR), Dry Laser Diffraction Spectroscopy (DLD) and Powder Rheometer (FT4). The analysis of the result of PA12 sintering with the DBLS method was carried out in comparison with the classic pLS approach. As it has been shown, the DBLS approach allows to obtain comparable results for sintered parts compared to the pLS method. What is particularly important, it was shown that the post-process powder in the DBLS method has almost unchanged properties - the change in molecular weight and viscosity is at the level of the measurement error. Reducing thermal degradation is especially important in order to obtain continuous circulation of the powder in the manufacturing process. [Display omitted] •The processability of PA12 via Dual Beam Laser Sintering was confirmed.•Mechanical properties of PA12 parts produced by DBLS and pLS were comparable.•DBLS method limits the thermal degradation of PA12 powder.