Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds

[Display omitted] Rhodium(III) complexes catalyze the insertion of carbenoids generated from diazo compounds into E−H bonds (E = B, Si, N, but not C), although less efficiently than classical rhodium(II) carboxylates, despite formally higher oxidation state of the metal.

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Bibliographic Details
Published inMendeleev communications Vol. 32; no. 4; pp. 482 - 484
Main Authors Komarova, Alina A., Muratov, Dmitry V., Perekalin, Dmitry S.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.07.2022
Subjects
catalysis
cyclopentadienyl ligands
diazo compounds
insertion
rhodium complexes
cyclopentadienyl ligands
catalysis
insertion
diazo compounds
rhodium complexes
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Summary:[Display omitted] Rhodium(III) complexes catalyze the insertion of carbenoids generated from diazo compounds into E−H bonds (E = B, Si, N, but not C), although less efficiently than classical rhodium(II) carboxylates, despite formally higher oxidation state of the metal.
ISSN:0959-9436
DOI:10.1016/j.mencom.2022.07.017