Filling of Channels of the Zeolite Framework in Trigonal Polar Nonaborate Ва3Na0.9(OH)1.9[B9O16][B(OH)3]

Crystals of the new trigonal borate Ва 3 Na 0.9 (OH) 1.9 [B 9 O 16 ][B(OH) 3 ] (sp. gr. P 31 c , a = 10.23684(15) Å, c = 8.72926(13) Å) were prepared by the mild hydrothermal synthesis. The filling of the channels in the framework of the polar nonaborate was found to differ from that determined prev...

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Bibliographic Details
Published inCrystallography reports Vol. 68; no. 2; pp. 237 - 241
Main Authors Topnikova, A. P., Belokoneva, E. L., Dimitrova, O. V., Volkov, A. S., Zorina, L. V.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.04.2023
Springer Nature B.V
Subjects
Channels
Crystallography and Scattering Methods
Hydrothermal crystal growth
Molecular structure
Physics
Physics and Astronomy
Structure of Inorganic Compounds
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Summary:Crystals of the new trigonal borate Ва 3 Na 0.9 (OH) 1.9 [B 9 O 16 ][B(OH) 3 ] (sp. gr. P 31 c , a = 10.23684(15) Å, c = 8.72926(13) Å) were prepared by the mild hydrothermal synthesis. The filling of the channels in the framework of the polar nonaborate was found to differ from that determined previously. It is consistent with the main features of this structure type with the preservation of sassoline molecules in the channels. The structure contains an additional ОН group, which is involved in the coordination of Ва.
ISSN:1063-7745
1562-689X
DOI:10.1134/S1063774523020207