Hydrated Dodecatungstatosilicate Complex with Protonated 1,2-Phenylenediamine (C6H9N2)3(H3O)SiW12O40 · 8H2O: Synthesis and Crystal Structure

The hydrated dodecatungstatosilicate complex with protonated ortho -phenylenediamine (C 6 H 9 N 2 ) 3 (Н 3 O)SiW 12 O 40 · 8H 2 O has been synthesized and studied by X-ray diffraction. Crystals are triclinic, space group Р -1, a = 13.6817(5) Å, b =1 4.5915(5) Å, с = 15.8844(5) Å, α = 98.891(3)°, β =...

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Bibliographic Details
Published inRussian journal of inorganic chemistry Vol. 63; no. 7; pp. 894 - 898
Main Authors Stepnova, A. F., Kaziev, G. Z., Quinones, S. Holguin, Khrustalev, V. N., Shlyakhova, M. A.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.07.2018
Springer Nature B.V
Subjects
Chemistry
Chemistry and Materials Science
Coordination Compounds
Crystal structure
Diffraction
Inorganic Chemistry
Phenylenediamine
X-ray diffraction
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Summary:The hydrated dodecatungstatosilicate complex with protonated ortho -phenylenediamine (C 6 H 9 N 2 ) 3 (Н 3 O)SiW 12 O 40 · 8H 2 O has been synthesized and studied by X-ray diffraction. Crystals are triclinic, space group Р -1, a = 13.6817(5) Å, b =1 4.5915(5) Å, с = 15.8844(5) Å, α = 98.891(3)°, β = 101.836(3)°, γ = 114.156(2)°, V = 2729.05(16) Å 3 , ρcalcd = 4.100 g/cm 3 , Z = 2.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023618070227