Alkylation of 1-(prop-2-ynyl)piperidine with СН-acids in ihe presence of mercury(II) acetate

General regilarities of the reaction of C-nucleophiles with 1-(prop-2-ynyl)piperidine in the presence of mercuty(II) acetate to form mono-and dicarbonyl derivatives of piperidine and bis[3-(piperidin-1-yl)prop-1-ynyl]mercury. Conditions of these reactions were optimized.

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Bibliographic Details
Published inRussian journal of general chemistry Vol. 87; no. 1; pp. 29 - 32
Main Authors Hobosyan, N. G., Balyan, K. V., Petrosyan, A. L., Hovakimyan, S. A., Chobanyan, Zh. A., Nersisyan, R. S.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 2017
Springer Nature B.V
Subjects
Alkylation
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Mercury acetate
Nucleophiles
Piperidine
acetylacetone
acetoacetic ester
alkylationе
prototropic isomers
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Summary:General regilarities of the reaction of C-nucleophiles with 1-(prop-2-ynyl)piperidine in the presence of mercuty(II) acetate to form mono-and dicarbonyl derivatives of piperidine and bis[3-(piperidin-1-yl)prop-1-ynyl]mercury. Conditions of these reactions were optimized.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363217010066