Synthesis of superdispersed surface phases: An example from the sulfidization of thin metallic films

The chemical composition and forms of element present in superdispersed (nanosized) surface phases were studied by X-ray photoelectron spectroscopy and X-ray spectral electron probe microanalysis. The phases were obtained during the sulfidization of thin metallic films of iron and copper on monocrys...

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Published inBulletin of the Russian Academy of Sciences. Physics Vol. 74; no. 8; pp. 1073 - 1076
Main Authors Akimov, V. V., Gerasimov, I. N.
Format Journal Article
LanguageEnglish
Published Heidelberg Allerton Press, Inc 01.08.2010
Springer Nature B.V
Subjects
Arsenopyrite
Chalcopyrite
Chemical composition
Disorder
Electron probe microanalysis
Energy conservation
Hadrons
Heavy Ions
Metal films
Nuclear Physics
Phase composition
Phases
Photoelectron spectroscopy
Physics
Physics and Astronomy
Proceedings of the International Symposium “Order
Properties of Oxides (ODPO-12)
Single crystals
Spectroscopic analysis
Sulfidization
Sulfur
Thin films
X-rays
Chalcopyrite
Bornite
Arsenopyrite
Auger Spectroscopy
Copper Sulfide
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Summary:The chemical composition and forms of element present in superdispersed (nanosized) surface phases were studied by X-ray photoelectron spectroscopy and X-ray spectral electron probe microanalysis. The phases were obtained during the sulfidization of thin metallic films of iron and copper on monocrystals of arsenopyrite and chalcopyrite. The dependence of the phase composition and the stoichiometry of sulfide phases on the sulfur concentration in the system was determined by physicochemical modeling (minimization of the Gibbs energy).
ISSN:1062-8738
1934-9432
DOI:10.3103/S1062873810080101