A Novel 1D Organic Lead Halide Hybrid for Blue and White Dual Emission
In recent years, photoelectric performances of many low-dimensional metal halide hybrid materials have been researched and utilized in the domain of phosphors, light emitting diodes (LEDs) and photoelectric detection etc. Nevertheless, unlike two-dimensional (2D) ones, one-dimensional (1D) hybrids r...
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Published in | Key engineering materials Vol. 905; pp. 103 - 108 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Trans Tech Publications Ltd
04.01.2022
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Subjects | |
Online Access | Get full text |
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Summary: | In recent years, photoelectric performances of many low-dimensional metal halide hybrid materials have been researched and utilized in the domain of phosphors, light emitting diodes (LEDs) and photoelectric detection etc. Nevertheless, unlike two-dimensional (2D) ones, one-dimensional (1D) hybrids received less attention to study their structures and optical properties. Herein, we deal with luminous performance and photoluminescence mechanism for an original 1D organic-inorganic lead chloride hybrid C5H14N3PbCl3 which is abbreviated as TMGPbCl3 (TMG+ = 1, 1, 3, 3-tetramethyguanidine cation). According to photoluminescence spectra, its broadband white-light luminescence are dual emissions from organic component TMG+ peaked at 429 nm and self-trapped excitons (STEs) of inorganic metal halide octahedra peaked at 510 nm, respectively and this property make it to be a promising white-light phosphor. |
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Bibliography: | Selected peer-reviewed full text papers from the 9th Annual International Conference on Material Science and Engineering (ICMSE 2021), July 23-25, 2021, Guiyang, China |
ISSN: | 1013-9826 1662-9795 1662-9795 |
DOI: | 10.4028/www.scientific.net/KEM.905.103 |