The Morphology of the Alumina Films Formed tn The Anodization Process of Aluminium in the Orthophosphoric Acid Solution. The Co-Fe Alloys Electrodeposition Into Obtained Alumina Pores

• Published in: Archives of metallurgy and materials Vol. 59; no. 1; pp. 137 - 143
• Main Authors: Gumowska, W, Dobosz, I, Wrzoszczyk, B
• Format: Journal Article
• Language: English
• Published: Warsaw Polish Academy of Sciences 01.03.2014
• Subjects: Acids; Alloys; Alumina; Aluminium; Aluminum; Aluminum oxide; Anodizing; Anodizing baths; Cobalt base alloys; Composition; Electrodeposition; Electrolysis; Electrolytes; Hydrogen; Iron; Membranes; Morphology; Nanowires; Oxidation; Oxide coatings; Porosity; Process parameters; Thickness
• ISSN: 1733-3490; 2300-1909
• DOI: 10.2478/amm-2014-0022

Abstract The optimal parameters of the anodic oxidation of aluminium in orthophosphoric acid solution was determined. In the pores of the obtained Al 2 O 3 membranes with the ordered nanometric structure Co-Fe alloys were electrodeposited. The Al 2 O 3 membranes were obtained in the two-stage anodic oxidation of aluminium in the 0.17 M H 3 PO 4 solution in the temperature 1°C and at the electrolysis voltage 180 V. The influence of the anodizing process parameters on the thickness of oxide films and the diameter of pores and the distance between them in the alumina membranes were determined. The electrodeposition of Co-Fe alloys was carried out from sulphate baths containing sulphates (VI) of copper (II) and cobalt (II) of different composition, in potentiostatic conditions. The optimal electrolysis conditions were determined, where the cathodic deposits of the best quality were obtained. The conditions are: the electrolyte composition: 0.3 M Fe; 0.5 M Co; pH = 3, the potential: -0.760 V (vs. SHE 1 )).