Intensity and composition-dependent sign reversal of non-linearity in TiO2/CeO2 nanocomposites

CeO2/TiO2 composite nanoparticles with different Ce/Ti molar ratios have been successfully synthesized via sol-gel method. It was found that the band gap of the nanocomposite is tunable by varying Ce/Ti content. The nonlinear response of the sample was studied by using the nanosecond laser pulses fr...

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Bibliographic Details
Published in中国物理B：英文版 no. 3; pp. 298 - 302
Main Author S. Divya V. R N. Nampoori E Radhakrishnan A. Mujeeb
Format Journal Article
LanguageEnglish
Published 01.03.2014
Subjects
YAG激光器
反转
复合纳米粒子
强度
材料组成
纳米复合材料
非线性响应
非线性折射率
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Summary:CeO2/TiO2 composite nanoparticles with different Ce/Ti molar ratios have been successfully synthesized via sol-gel method. It was found that the band gap of the nanocomposite is tunable by varying Ce/Ti content. The nonlinear response of the sample was studied by using the nanosecond laser pulses from a Q switched Nd：Yag laser employing the Z-scan method. Open aperture Z-scan experiment revealed that with the increase in the CeO2 amount in the nanocomposite, the non-linearity of the composite increases, and it was assumed that this could be due to the modification of TiO2 dipole symmetry by the addition of CeO2. Closed aperture Z-scan experiment showed that when the CeO2 amount increases, positive nonlinear refraction decreases, and this could be attributed to the increase in the two photon absorption which subsequently suppresses the nonlinear refraction.
Bibliography:CeO2/TiO2 composite nanoparticles with different Ce/Ti molar ratios have been successfully synthesized via sol-gel method. It was found that the band gap of the nanocomposite is tunable by varying Ce/Ti content. The nonlinear response of the sample was studied by using the nanosecond laser pulses from a Q switched Nd：Yag laser employing the Z-scan method. Open aperture Z-scan experiment revealed that with the increase in the CeO2 amount in the nanocomposite, the non-linearity of the composite increases, and it was assumed that this could be due to the modification of TiO2 dipole symmetry by the addition of CeO2. Closed aperture Z-scan experiment showed that when the CeO2 amount increases, positive nonlinear refraction decreases, and this could be attributed to the increase in the two photon absorption which subsequently suppresses the nonlinear refraction.
sol-gel method, non-linearity, Z-scan experiment, reversesaturation absorption curve
11-5639/O4
ISSN:1674-1056
2058-3834
DOI:10.1088/1674-1056/23/3/034209