Copper abietate/polyvinyl acetate composite film for enhanced humidity sensing in Chinese herbal medicine monitoring systems

• Published in: Sensors and actuators. B, Chemical Vol. 422; p. 136656
• Main Authors: Tan, Ningning, Weng, Yaohang, Li, Haijun, Chen, Bo, Zhao, Lan, Huang, Biao, Lu, Beili, Tang, Lirong
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.01.2025
• Subjects: Chinese herbal medicine; Copper abietate/Polyvinyl acetate; Humidity sensing; Renewable; Wireless environmental monitoring; Wireless environmental monitoring; Chinese herbal medicine; Copper abietate/Polyvinyl acetate; Renewable; Humidity sensing
• ISSN: 0925-4005
• DOI: 10.1016/j.snb.2024.136656

Sensing materials derived from natural and biodegradable sources are increasingly being developed and applied to realize environmentally friendly technologies. In this paper, we present the synthesis, characterization, and application of a novel copper abietate/polyvinyl acetate (CuA/PVAc) composite film, specifically engineered to enhance the humidity-sensing capabilities of Chinese herbal medicine monitoring systems. The sensing material was synthesized by strategically melding copper abietate, a natural renewable material, with PVAc to exploit their combined synergistic properties for optimal humidity-sensing performance. Comprehensive characterization techniques, including inductively coupled plasma optical emission spectrometry (ICP-OES), field-emission scanning electron microscopy (FESEM), water contact angle measurements, and Fourier transform infrared (FT-IR) spectroscopy, were employed to confirm the formation of CuA/PVAc composites. These analyses confirmed the homogeneity and intended chemical composition of the composite films.The resultant CuA-1/PVAc-4 (0.4 μg/μL) composite film exhibited a good logarithmic relation (0.9988) with relative humidity (RH) over a wide range (11 %–97 %) and high sensitivity (24.55 Hz/%RH). Moreover, this study introduces a novel, eco-friendly approach by integrating the CuA/PVAc composite with a quartz crystal microbalance (QCM) sensor and a sophisticated wireless circuit that enables real-time, Wi-Fi-based humidity monitoring tailored for the preservation of Chinese herbal medicines. The implementation of this wireless humidity detection system represents a significant advancement in the application of environmentally friendly materials in sensor technology and offers a practical and scalable approach for precise environmental monitoring. [Display omitted] •Rosin hydrophobic groups contribute to the high humidity sensing stability of sensitive films.•Copper abietate is complexed with PVAc to enhance the film’s adhesion to QCMs.•The GA-BP algorithm is introduced for temperature compensation in the design of QCM test system.