Hydrothermally synthesized copper telluride nanoparticles: First approach to flexible solid-state symmetric supercapacitor

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 498; p. 155284
• Main Authors: Patil, Girish P., Jadhav, Chandradip D., Lyssenko, Svetlana, Minnes, Refael
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.10.2024
• Subjects: Copper Telluride; Electrode; Flexible Solid-State Device; Gel Polymer Electrolyte; Nanoparticles; Supercapacitor; Nanoparticles; Supercapacitor; Copper Telluride; Flexible Solid-State Device; Electrode; Gel Polymer Electrolyte
• ISSN: 1385-8947
• DOI: 10.1016/j.cej.2024.155284

[Display omitted] •Cu2-xTe nanoparticles explored for supercapacitor electrodes.•Small size (38 nm) and high crystallinity enhance charge storage.•Fabricated flexible, symmetric supercapacitors in PVA-LiClO4 gel.•Devices show 11 Wh/kg energy density, 800 W/kg power density.•Maintain 85% stability after 5000 cycles. Supercapacitors, with their high-power density, rapid charge–discharge rates, and long cycle life, have emerged as promising energy storage devices for numerous applications. Among the various materials explored for supercapacitor electrodes, copper-based chalcogenides have gathered significant attention due to their intriguing electrochemical properties and simple synthesis routes. While there have been thorough investigations in other fields, only a limited number of studies have focused on the specific application of copper telluride nanoparticles as supercapacitors. In this study, we present a novel approach utilizing hydrothermally synthesized copper telluride (Cu2-xTe) nanoparticles as binder-free electrodes on flexible stainless steel (SS) substrates. The Cu2-xTe nanoparticles, with their small particle (38 nm) and highly crystalline structure, enhance charge storage and promotes a pseudocapacitive behavior, resulting in a high specific capacitance [381 F/g (163 mF/cm2) at 2 mV/s] in a 2 M KCl electrolyte solution. Moreover, we studied and explained the distinct contributions of surface-controlled and diffusion-limited processes to the overall charge storage capacity of the electrode. Our pioneering effort includes the fabrication and analysis of flexible, symmetric solid-state supercapacitor devices utilizing Cu2-xTe electrodes with PVA-LiClO4 gel electrolyte. These devices demonstrate an energy density of 11 Wh/kg, a power density of 800 W/kg, and an impressive 85 % retention of cyclic stability after 5000 cycles.