INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY

On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral env...

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Published inJournal of engineering studies and research Vol. 26; no. 3; pp. 69 - 74
Main Authors SEYE, DAME, TOURE, ASSANE, DIOP, CHEIKH ABDOUL KHADIR, DIOP, LIBASSE
Format Journal Article
LanguageEnglish
Published Bacau Universitatea "Vasile Alecsandri" din Bacau 01.07.2020
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
Subjects
Ammonium bromides
Cadmium
Chains
Chemistry
Copper
Crystal structure
Hydrogen bonds
Inorganic chemistry
intermolecular hydrogen bonds, discrete structures, infinite chain, supramolecular architecture
Ligands
Nickel
Niobium
France
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Summary:On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral environments around the metallic centres. The MX2 behaves as discrete chains. For most of the structures, when intermolecular hydrogen bonds are considered, supramolecular architectures may be obtained.
ISSN:2068-7559
2344-4932
DOI:10.29081/jesr.v26i3.208