Chemie polyfunktioneller Liganden, 69 [1] Über drei Organo-Arsen-Käfigverbindungen mit Noradamantanstruktur / Chemistry of Polyfunctional Ligands, 69 [1] Three Organo-Arsenic Cage Compounds with Noradamantane Structure

The reaction of l.l.l-tris(diiodarsinomethyl)ethane, CH C(CH Asl (1), with H C(COOC , H C(COOCH and H C(COC in presence of the auxiliary base (C N gives the noradamantane structured compounds CH C(CH As) [E=C(COOC H (2), C(COOCH (3) and C(COC (4)]. The new compounds have been characterized by mass s...

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Published inZeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 36; no. 12; pp. 1532 - 1537
Main Authors Ellermann, Jochen, Lietz, Martin
Format Journal Article
LanguageEnglish
Published Verlag der Zeitschrift für Naturforschung 01.12.1981
Subjects
1H NMR Spectra
Arsenic Cage Compounds
Mass Spectra
Synthesis
Vibrational Spectra
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Summary:The reaction of l.l.l-tris(diiodarsinomethyl)ethane, CH C(CH Asl (1), with H C(COOC , H C(COOCH and H C(COC in presence of the auxiliary base (C N gives the noradamantane structured compounds CH C(CH As) [E=C(COOC H (2), C(COOCH (3) and C(COC (4)]. The new compounds have been characterized by mass spectrometry and infrared, Raman and H NMR spectroscopy.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1981-1209