Reaction of 1-aminoisoindole with 1,4-naphthoquinone and study of the product by spectroscopic methods

In our previous researches we have shown, that 1-aminoisoindole, which exists predominantly in isoindoline tautomeric form, can undergo [4+2]-cycloaddition reactions with maleimides according to the Curtin-Hammet principle. We continued to study this reaction, but with another dienophile – 1,4-napht...

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Bibliographic Details
Published inFrench-Ukrainian journal of chemistry Vol. 6; no. 2; pp. 27 - 31
Main Authors Levkov, Igor, Yegorova, Tetyana, Kysil, Andriy, Vedrenne, Marc, Voitenko, Zoia
Format Journal Article
LanguageEnglish
Published 2018
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Summary:In our previous researches we have shown, that 1-aminoisoindole, which exists predominantly in isoindoline tautomeric form, can undergo [4+2]-cycloaddition reactions with maleimides according to the Curtin-Hammet principle. We continued to study this reaction, but with another dienophile – 1,4-naphtoquinone. In this case, the reaction does not stop when the bis-Michael adduct is obtained, but continues with the formation of a more complex compound, the structure of which we have studied by two-dimensional NMR spectroscopic methods.
ISSN:2312-3222
2312-3222
DOI:10.17721/fujcV6I2P27-31