Transglycosylation Reaction: Synthesis and Supramolecular Study of Carbohydrate‐Cased C 2 ‐Symmetric 20‐ and 22‐Membered Macrocyclic Dinucleosides

Abstract Bis‐uracil nucleoside, in which the nucleobase is anchored to C 2 ‐symmetric 22‐membered macrocycle (CSM‐3), was synthesized by nucleosidation of 1,2‐isopropylidenefuranose ring‐fused macrocycle. The bis‐uracil nucleoside exhibited petal flake‐like morphology in ethanolic solution. A change...

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Published inChemistrySelect (Weinheim) Vol. 8; no. 8
Main Authors Hudait, Nandagopal, Karmakar, Arun, Basu, Arpan, Kar, Binoy, Bhuyan, Samuzal, Chhetri, Karan, Kundu, Subrata, Gopal Roy, Biswajit, Sengupta, Jhimli
Format Journal Article
LanguageEnglish
Published 23.02.2023
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Summary:Abstract Bis‐uracil nucleoside, in which the nucleobase is anchored to C 2 ‐symmetric 22‐membered macrocycle (CSM‐3), was synthesized by nucleosidation of 1,2‐isopropylidenefuranose ring‐fused macrocycle. The bis‐uracil nucleoside exhibited petal flake‐like morphology in ethanolic solution. A change from petal‐like to bundle‐like morphology was observed on the addition of N 6 ‐aminobenzoyl purine to the bis‐uracil nucleoside.
ISSN:2365-6549
2365-6549
DOI:10.1002/slct.202204311