Organic compounds of gallium. III. Reactions of gallium alkoxides with acetylacetone, ethyl acetoacetate, methyl acetoacetate, and methyl salicylate
Derivatives of gallium of the type: Ga(i-C 3 H 7 O) 3−x lig x (x = 1, 2, or 3; and H lig = acetylacetone, methyl and ethyl acetoacetate, or methyl salicylate) have been synthesized by reacting gallium alkoxides with ligands in various molar ratios. The compounds are soluble in organic solvents and c...
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| Published in | Canadian journal of chemistry Vol. 47; no. 14; pp. 2661 - 2663 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Ottawa, Canada
NRC Research Press
15.07.1969
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| Online Access | Get full text |
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| Summary: | Derivatives of gallium of the type: Ga(i-C
3
H
7
O)
3−x
lig
x
(x = 1, 2, or 3; and H lig = acetylacetone, methyl and ethyl acetoacetate, or methyl salicylate) have been synthesized by reacting gallium alkoxides with ligands in various molar ratios. The compounds are soluble in organic solvents and could be volatilized under reduced pressure. Their molecular weights have been determined ebullioscopically. The infrared spectra of some of the compounds have been studied. |
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| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v69-437 |