Studies on Nitro Sugars. VI. Synthesis of Methyl 2-Deoxy-2-nitro-α-D-glucopyranoside Derivatives
Oxidation of methyl 3-O-benzyl-4,6-O-benzylidene-2-oximino-α-D-arabino-hexopyranoside (5) with trifluoroperoxyacetic acid afforded in 76% yield the corresponding 2-nitro-glucopyranoside (6) which has a twist-boat conformation in chloroform.
Saved in:
| Published in | Bulletin of the Chemical Society of Japan Vol. 48; no. 11; pp. 3413 - 3414 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
The Chemical Society of Japan
01.11.1975
|
| Online Access | Get full text |
Cover
Loading…
| Summary: | Oxidation of methyl 3-O-benzyl-4,6-O-benzylidene-2-oximino-α-D-arabino-hexopyranoside (5) with trifluoroperoxyacetic acid afforded in 76% yield the corresponding 2-nitro-glucopyranoside (6) which has a twist-boat conformation in chloroform. |
|---|---|
| ISSN: | 0009-2673 1348-0634 |
| DOI: | 10.1246/bcsj.48.3413 |