Synthesis and Characterization of Ti-13Ta-6Sn Foams Produced Using Mechanical Alloying, the Space Holder Method and Plasma-Assisted Sintering

• Published in: Metals (Basel ) Vol. 14; no. 10; p. 1145
• Main Authors: Cavilha Neto, Francisco, Medeiros, Vagner Kretiska, Salinas-Barrera, Vicente, Pio, Edgar, Aguilar, Claudio, Ramos, Bruno Borges, Klein, Aloísio Nelmo, Henriques, Bruno, Binder, Cristiano
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 08.10.2024
• Subjects: Additive manufacturing; Alloy powders; Alloys; Biocompatibility; Bones; Cold pressing; elastic modulus; Foamed metals; Fractions; implant; Injection molding; Mechanical alloying; Mechanical properties; Modulus of elasticity; Plasma; porous titanium; Potassium; Sintering; Sintering (powder metallurgy); space holder; Stress shielding; Titanium; Transplants & implants
• ISSN: 2075-4701; 2075-4701
• DOI: 10.3390/met14101145

Highly porous titanium foams are great candidates for replacing bone structures with a low elastic modulus owing to their ability to avoid the stress shielding effect. However, the production of highly porous foams (>70 vol.%) with well-distributed, stable, and predictable porous architectures using powder compaction and space holders is challenging. In this study, pure titanium powder and mechanically alloyed Ti-13Ta-6Sn were mixed with 50, 70, and 80 vol.% KCl powders as a space holder, cold-compacted, and sintered in a plasma-assisted sintering reactor to produce highly porous foams. The space holder was completely removed using heat and plasma species collisions prior to sintering. A Ti-13Ta-6Sn alloy powder with α, β, and metastable FCC-γ phases was synthesized. The characteristics of the alloyed powder, mixing step, and the resulting sintered samples were compared to those of CP-Ti. After sintering, the alloy exhibited α and β phases and a reduced elastic modulus. Foams with an elastic modulus in the range of the cortical and trabecular bones were obtained. The results showed the effects of the space holder volume fractions on the volume fraction, size, distribution, interconnectivity, and shape of the pores. The Ti-13Ta-6Sn foams exhibited a uniform open-celled porous architecture, lower elastic modulus, higher yield strength, and higher passivation resistance than CP-Ti. Ti-13Ta-6Sn exhibited a nontoxic effect for the mouse fibroblast cell line.