Thermometry and up-conversion luminescence of Ln3+ (Ln = Er, Ho, Tm)-doped double molybdate LiYbMo2O8

• Published in: Journal of materials science. Materials in electronics Vol. 31; no. 21; pp. 18370 - 18380
• Main Authors: Yun, Xiangyan, Zhou, Jun, Zhu, Yaohui, Molokeev, Maxim S., Jia, Yetong, Wei, Chao, Xu, Denghui, Sun, Jiayue
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.11.2020; Springer Nature B.V
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Crystal structure; Emission; Energy; Energy levels; Fluorescence; High temperature; Holmium; Luminescence; Materials Science; Optical and Electronic Materials; Optical properties; Phosphors; Photons; Physics; Sensitivity; Sensors; Temperature sensors; Thermometry; Thulium; Upconversion
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-020-04382-8

The discovery of stable and highly sensitive up-conversion (UC) phosphors using the fluorescence intensity ratio (FIR) is a significant challenge in the field of optical temperature sensor. Er 3+ /Ho 3+ /Tm 3+ -doped LiYbMo 2 O 8 UC phosphors with excellent luminescence properties were successfully synthesized through a high-temperature solid-state reaction, and the crystal structure and UC luminescence properties were discussed in detail. The UC process has been investigated by spectra pump power dependence and further explained via the energy level diagram. All emission processes about Er 3+ ions and Ho 3+ ions are two-photon processes and the blue emission process about Tm 3+ ions is a combination of two-photon process and three-photon process. Thermal sensing performances depended on FIR technology were estimated and the sensitivities of LiYb 1− x Mo2O8: x Ln 3+ included absolute sensitivity ( S a ) and relative sensitivity ( S r ) can produce particular change rules with the temperature, which can serve as excellent candidates for applications in optical temperature sensing. With the increase of temperature, the maximum values of S r of LiYb 1− x Mo 2 O 8 : x Ln 3+ are 1.16% K −1 (0.05Er 3+ ), 0.25% K −1 (0.01Ho 3+ ), and 0.51% K −1 (0.01Tm 3+ ), respectively. In addition, the S a value of LiYb 0.95 Mo 2 O 8 :0.05Er 3+ phosphor will reach the maximum (1.08% K −1 ) at 475 K, while the maximum values of S a of LiYb 0.99 Mo 2 O 8 :0.01Ho 3+ and LiYb 0.99 Mo 2 O 8 :0.01Tm 3+ are 0.16% K −1 , 0.14% K −1 .