A Black Phosphorus–Graphite Composite Anode for Li‐/Na‐/K‐Ion Batteries

• Published in: Angewandte Chemie Vol. 132; no. 6; pp. 2338 - 2342
• Main Authors: Jin, Hongchang, Wang, Haiyun, Qi, Zhikai, Bin, De‐Shan, Zhang, Taiming, Wan, Yangyang, Chen, Jiaye, Chuang, Chenghao, Lu, Ying‐Rui, Chan, Ting‐Shan, Ju, Huanxin, Cao, An‐Min, Yan, Wensheng, Wu, Xiaojun, Ji, Hengxing, Wan, Li‐Jun
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 03.02.2020
• Subjects: Alkali metals; Alkalimetall-Ionen-Batterien; Anodenmaterialien; Anodes; Batteries; Bildungsenergie; Chemical reactions; Chemistry; Comparative studies; Diffusion coefficient; Electrochemistry; Electrode materials; Free energy; Gravimetry; Heat of formation; Ion currents; Ion diffusion; Ion storage; Ionendiffusionskoeffizient; Ions; Lithium; Metal ions; Phosphorus; Redox reactions; Schwarzer Phosphor; Sodium; Spectroscopy

Black phosphorus (BP) is a desirable anode material for alkali metal ion storage owing to its high electronic/ionic conductivity and theoretical capacity. In‐depth understanding of the redox reactions between BP and the alkali metal ions is key to reveal the potential and limitations of BP, and thus...